Hydrothermal carbonization of garden waste by pretreatment with anaerobic digestion to improve hydrohcar performance and energy recovery
2022
Wang, Yanshan | Li, Yihang | Zhang, Yingxiu | Song, Yingjin | Yan, Beibei | Wu, Wenzhu | Zhong, Lei | Li, Ning | Chen, Guanyi | Hou, Li'an
Sustainable and resourceful utilization of garden waste with high lignocellulosic content remains a huge challenge, anaerobic digestion (AD) and hydrothermal treatment provide prospective technologies with achieving environmental and economic benefits. In this study, a 7–28 d AD was provided as a biomass pretreatment means and combined with hydrothermal carbonization (HTC) to treat three typical garden wastes (leaves, branches, grass). The results showed that AD pretreatment could effectively change the surface composition and structure properties of the feedstocks and thus modulating the properties of the hydrochar downstream. Compared to the unpretreatment samples, the specific surface area (SSA), higher heating value (HHV), energy density and nutrient elements (P and K) of hydrochar obtained by AD pretreatment were significantly improved and enriched, respectively. Specifically, the highest HHV of hydrochar obtained from leaves, branches, and grass were 25.71, 25.63, and 23.81 MJ/kg, which obtained with 21, 14, and 7 d of AD pretreatment respectively. The P contents of hydrochar of leaves and grass pretreated with AD for 14 and 7 d were 205% and 15% higher than those without AD pretreatment, respectively. Additionally, in this coupled system, the biomass energy recovery of 90.2% (78.2% biochar and 12.0% CH₄) was achieved on leaves pretreated with AD for 21 d. Energy recovery of 81.2% (66.8% biochar, 14.4% CH₄) and 71.3% (39.7% biochar, 31.6% CH₄) was obtained by 14 d of AD pretreatment on branches and grass, respectively. Thus, this study enhances energy utilization efficiency and reduces secondary waste generation, providing valuable new insights into AD coupled with HTC technology.
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