Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes
2011
Luo, Xiaoyan | Zhou, Zhiqiang | Li, Xin | Liang, Xinmiao | Ye, Jinxing
The enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes with diaryl phosphine oxides is explored for the first time using (S)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine as a catalyst. It afforded 1,4-addition adducts in good to excellent yields with up to 99% ee.
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书目信息
出版者
Elsevier Ltd
其它主题
Enantioselectivity; Organosilicon compounds
语言
英语
类型
Journal Article; Text
2024-02-27
MODS