Phosphorus adsorption by sediment considering mineral composition and environmental factors
2021
Li, Xiaocui | Huang, Lei | Fang, Hongwei | Chen, Minghong | Cui, Zhenghui | Sun, Zhiyu | Reible, Danny
Sediment, composed of a complex assemblage of minerals, controls the fate and behaviour of P in aqueous environments and affects trophic status. In this study, P adsorption was studied on minerals including quartz, hematite, potassium feldspar, montmorillonite, kaolin, and calcite (i.e., the main components of sediment) and sediment from the Guanting Reservoir. A general formula for P adsorption was proposed that considers mineral composition through the component additivity method, also incorporating the effects of environmental factors, including the aqueous P concentration (Cₑ), pH, sediment concentration (S), and ionic strength (IS). The P adsorption capacity gradually decreased with increasing particle size, and the contributions from kaolin and montmorillonite to P adsorption were significant despite representing only a small fraction of sediment (with a maximum amount of P adsorption of 0.92 and 0.36 mg/g, respectively). The content of quartz accounted for approximately 40–60% of sediment; however, its P adsorption capacity was only 0.13 mg/g. These minerals exhibited different adsorption characteristics due to their different surface morphologies and lattice structures. Multivariable regression analysis was used to show that the amount of P adsorption was strongly correlated with Cₑ, followed by S, IS, and pH.
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