Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
2018
Carter, Joseph H. | Han, Xue | Moreau, Florian Y. | da Silva, Ivan | Nevin, Adam | Godfrey, Harry G. W. | Tang, Chiu C. | Yang, Sihai | Schröder, Martin
We report a record-high SO₂ adsorption capacity of 12.3 mmol g–¹ in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO₂ adsorption in MFM-601 is fully reversible and highly selective over CO₂ and N₂. The binding domains for adsorbed SO₂ and CO₂ molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.
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书目信息
Journal of the American Chemical Society
卷
140
期
46
页码
15564
- 15567
ISSN
1520-5126
出版者
Blackwell Science
其它主题
Coordination polymers; X-ray diffraction; Porous media
语言
英语
许可
//data.crossref.org/schemas/AccessIndicators.xsd:license_ref>http://purl.org/eprint/accessRights/OpenAccess | //data.crossref.org/schemas/AccessIndicators.xsd:program>//data.crossref.org/schemas/AccessIndicators.xsd:license_ref> | //data.crossref.org/schemas/AccessIndicators.xsd:program>
类型
Text; Journal Article
2024-02-28
MODS
