Binary self-assembly of ordered Bi4Se3/Bi2O2Se lamellar architecture embedded into CNTs@Graphene as a binder-free electrode for superb Na-Ion storage
2022
Liu, Honglang | Li, Dan | Liu, Hanhao | Wang, Chao | Wang, Yanzhong | Chen, Yanjun | Linghu, Yaoyao | Tian, Zhen | Song, Huaihe | Zhou, Jisheng | Guo, Li
With the development of various flexible electronic devices, flexible energy storage devices have attracted more research attention. Binder-free flexible batteries, without a current collector, binder, and conductive agent, have higher energy density and lower manufacturing costs than traditional sodium-ion batteries (SIBs). However, preparing binder-free anodes with high electrochemical performance and flexibility remains a great challenge. In this study, a binary self-assembly composite of an ordered Bi₄Se₃/Bi₂O₂Se lamellar architecture wrapped by carbon nanotubes (CNTs) was embedded in graphene with strong interfacial interaction to form Bi₂O₂Se/Bi₄Se₃@CNTs@rGO (BCG), which was used as a binder-free anode for SIBs. A unique “one-changes-into-two” phenomenon was observed: the layered Bi₂Se₃ was transformed into a unique layered Bi₄Se₃/Bi₂O₂Se heterojunction structure, which not only provides more electrochemical channels but also reduces internal stress to improve the stability of the material structure. BCG-2 showed excellent sodium-ion storage, delivering a reversible capacity of 346 mA h/g at 100 mA/g and maintaining a capacity of 235 mA h/g over 50 cycles. Even at a high current density of 1 A/g, it retains a capacity of 105 mA h/g after 1000 cycles. This unique design concept can also be employed in synthesizing other binder-free electrodes to improve their properties.
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