Efficient visible light-driven water oxidation catalysts based on B-β-{BiW₈O₃₀} and unique 14-nuclear hetero-metal sandwich unit

Gong, Lige; Yu, Li; Yu, Kai; Ding, Yong; Lv, Jinhua; Wang, Chunmei; Su, Zhanhua; Zhou, Baibin

Efficient visible light-driven water oxidation catalysts based on B-β-{BiW₈O₃₀} and unique 14-nuclear hetero-metal sandwich unit

2018

A sandwich tungstobismuthate with new topology based on {B-β-BiW₈O₃₀}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O₂ yield of 32.88%.

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