Copper-catalyzed diesterification of 1,3-diene for the synthesis of allylic diester compounds
2016
Qian, Bo | Xiong, Haigen | Zhu, Nengbo | Ye, Changqing | Jian, Wujun | Bao, Hongli
A novel and atom economical copper-catalyzed diesterification of 1,3-dienes has been developed; the available allylic diester derivatives, which are the important intermediates for the synthesis of natural products, were attained with moderate to good yields. Preliminary mechanistic study suggests that allylic radical might be involved in this transformation.
显示更多 [+] 显示较少 [-]AGROVOC关键词
书目信息
出版者
Elsevier Ltd
其它主题
Allylic radical; 3-dienes; Diesterification; Aryl diacyl peroxide; Allylic diester
语言
英语
类型
Journal Article; Text
2024-02-28
MODS