Retention of pesticides and metabolites by nanofiltration by effects of size and dipole moment
2013
Musbah, I. | Cicéron, D. | Saboni, A. | Alexandrova, S.
This study is focused on the possibility of pesticide and DEA elimination by nanofiltration using NF and OPMN-K membranes. Experiments are carried out on laboratory equipment in batch circulation and applied pressures vary between 10 and 25bars. Three common pesticides (simazine, atrazine, diuron) and a chlorinated metabolite of atrazine: diethylatrazine is used as solutes, either alone or in complex solutions. For all experiments, NF shows better performance compared to OPMN-K. The most retained pesticide is atrazine and the least retained is diuron due to its higher dipole moment (high carbonyl group contribution) coupled to linear form which may also induce a decrease in its steric retention. In the case of pesticide/DEA mixtures, DEA rejection is better (up to 44%) for all pressures due to the formation of macromolecular complexes. It is also noticed that molecular weight and size, expressed by Stokes radius, are not the only parameters influencing rejection: shape of the molecule (molecular length and width) has a strong influence on rejection. The observed rejection increases when length and width increase. The nanofiltration technology seems to be a good way to treat the problem of pesticide pollution in one step process.
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