Selective Intermolecular Oxidative Cross-Coupling of Enolates
2015
Selective intermolecular oxidative cross-coupling of enolates, which is a bond-forming reaction between carbanion equivalents, remains as an unsolved issue despite its potential utility for the direct synthesis of unsymmetrical 1,4-diones. The main difficulty derives from the unavoidable homo-coupling. Our strategy depends on the selective one-electron oxidation of one enolate to afford an electrophilic carbonyl α-radical species, followed by trapping with another enolate. The present study demonstrates the selective oxovanadium(V)-induced cross-coupling between boron and silyl enolates.
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书目信息
Journal of the American Chemical Society
卷
137
期
32
页码
10072
- 10075
ISSN
1520-5126
出版者
Springer US
语言
英语
类型
Journal Article; Text
2024-02-28
MODS