Solvent-promoted highly selective dehydrogenation of tetrahydroisoquinolines without catalyst and hydrogen acceptor
2016
An unusual solvent DMF-promoted dehydrogenation of 1-substituted 1,2,3,4-tetrahydroisoquinolines to synthesize cyclic imines is described. This environmentally friendly reaction features no requirement of any metal catalysts, oxidants, or hydrogen acceptors. A wide range of structurally varied 3,4-dihydroisoquinolines can be obtained with good yields and excellent chemoselectivities.
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书目信息
出版者
Elsevier B.V.
其它主题
Dehydrogenation; Tetrahydroisoquinoline; Imine; Partial dehydrogenation; Tetrahydroisoquinolines
语言
英语
类型
Journal Article; Text
2024-02-28
MODS