Excellent photocatalytic performances of Co3O4–AC nanocomposites for H2 production via wastewater splitting
2022
Sekar, Sankar | Preethi, V. | Caravaṇan̲, Nallūr Cā. | Kim, Tŭng-nyong | Lee, Sejoon
Natural sunlight-driven photocatalytic hydrogen production from wastewater is one of the most desirable techniques that can realize future green energy technology. Herein, we report the synthesis and the characterization of the biomass activated carbon (AC)-decorated cobalt oxide (Co₃O₄) nanocomposites for solar-stimulated photocatalytic hydrogen production from sulphide wastewater. The Co₃O₄-AC nanocomposites were ultrasonically synthesized by using hydrothermally-grown spinel Co₃O₄ nanoflakes and biomass-derived AC nanoflakes. Co₃O₄-AC showed a nanobundle-like aggregated morphology, and exhibited a large specific surface area (~133 m²/g). Through utilizing Co₃O₄-AC as a photocatalyst for photocatalytic splitting of sulphide wastewater (0.2 M) under solar irradiance with 730 W/m², an enhanced H₂ production efficiency (~70 mL/h) was achieved owing to the synergic effects from 2-dimentionally configured Co₃O₄ and AC microstructures; i.e., large surface area of Co₃O₄ and high electrical conductivity of AC. These findings suggest the nanocomposites of Co₃O₄-AC to hold great promise for the green approach of photocatalytic wastewater splitting.
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