Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines
2016
Iron complex-catalyzed regioselective single hydrophosphination of terminal arylalkynes with secondary phosphines was achieved. Unsymmetric 1,2-bis(phosphino)ethanes with different phosphino groups were obtained by using our catalytic systems. The structures of the obtained vinylphosphine, unsymmetric 1,2-bis(phosphino)ethane, and iron catalyst precursors were confirmed by single crystal X-ray diffraction studies.
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书目信息
Chemical communications
卷
52
期
15
页码
3163
- 3166
ISSN
1364-548X
出版者
Taylor & Francis
其它主题
Regioselectivity; Alkynes
语言
英语
类型
Text; Journal Article
2024-02-28
MODS