The rearrangement of phenyllactate in the biosynthesis of tropic acid
1994
Phenyl[1,3-13C,]lactic acid was synthesized and fed to Datura stramonium via the wick method and via the roots. Hyoscine (scopolamine) and hyoscyamine were isolated, and examination of their 13C NMR spectra showed spin-spin coupling from the newly formed contiguous centres, indicating that tropic acid is formed by an intramolecular rearrangement of phenyllactate.
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书目信息
出版者
Elsevier
其它主题
Molecular conformation; Phenyllactic acid; Hyoscine; Tropane alkaloids
语言
英语
注释
Part 5 if the series "the biosynthesis of tropic acid".
2019-12-05
类型
Journal Article; Text
2024-02-28
MODS