Novel Enantiomerically Pure Ferrocenes
2014
Zeijden, Adolphus A . H van der | Sieler, J. | Hovestreydt, E.
A chiral ferrocene (Cpᴱ₂Fe) was synthesized by reaction of CpᴱLi with FeCl₂(THF)₁.₅ The cyclopentadienyl ligand Cpᴱ contains a dimethylamino group that is separated from the Cp backbone by two stereogenic carbon centres. Reaction of Cpᴱ₂Fe with excess Mel affords the ammonium salt Cpᴱ₂Fe.2MeI. Its solid state structure was determined by X-ray diffraction methods.
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书目信息
Zeitschrift für Naturforschung B
卷
51
期
3
页码
437
- 440
ISSN
1865-7117
出版者
Elsevier Ltd
其它主题
Crystal structure; Am m onium salt; X-ray diffraction; Ferrous chloride; Nitrogen-functionalized cyclopentadienyl ligand; Chiral cyclopentadienyl ligand; Ferrocene
语言
英语
类型
Text; Journal Article
2024-02-28
MODS
