Selective palladium-catalysed dimerisation of methyl acrylate in ionic liquids: towards a continuous process
2003
Picquet, Michel | Stutzmann, Stefanie | Tkatchenko, Igor | Tommasi, Immacolata | Zimmermann, Jörg | Wasserscheid, Peter
The activity and stability of cationic palladium complexes [Pd(PBu₃)₂S₂]²⁺ used for the selective tail-to-tail dimerisation of methyl acrylate are significantly improved with the utilisation of ionic liquids like [BMIM][BF₄] or the protonated N-butyl-imidazole, [HBIM][BF₄]. Problems related to product inhibition and catalyst recycling are overcome by running the reaction in a two-phase mode, toluene being used as extractant. Catalyst stabilisation is further improved by trapping the ancillary ligand into the ionic liquid with an ionic tail: with the use of 1-dibutylphosphino-2-dimethylaminoethane, the catalyst is stable for more than 100 h, therefore demonstrating the feasibility of a continuous process for methyl acrylate dimerisation.
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