Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity
2005
Muthusamy, Sengodagounder | Krishnamurthi, Janagiraman | Nethaji, Munirathnam
The reverse regio- and diastereoselectivities are observed between the reactions involving 5- and 6-membered-ring cyclic carbonyl ylide dipoles with α-methylene ketones. A mild catalytic route to synthesize spirocyclic systems with high regio-, chemo- and diastereoselectivities is described.
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书目信息
Chemical communications
                                                                
                                                                
                                                                
                                                                
                                                                    期
                                                                    30
                                                                
                                                                
                                                                
                                                                    
                                                                    页码
                                                                    3862
                                                                    
                                                                    
                                                                        - 3864
                                                                    
                                                                
                                                                
                                                                
                                                                
                                                                
                                                                    ISSN
                                                                    1364-548X
                                                                
                                                            出版者
                                            Blackwell Publishing Ltd
                                        其它主题
                                            Diastereoselective synthesis; Diastereoselectivity
                                        语言
                                            英语
                                        类型
                                            Journal Article; Text
                                        
                                            
                                            2024-02-28
                                        
                                        
                                        
                                        
                                            
                                            MODS