Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative Annulation
2016
Fukuzumi, Keita | Unoh, Yuto | Nishii, Yuji | Satoh, Tetsuya | Hirano, Koji | Miura, Masahiro
The dehydrogenative annulation of thiophen-2-carboxamides with 2 equiv of alkynes proceeds efficiently in the presence of a rhodium catalyst and a copper oxidant to furnish multiply substituted benzo[c]thiophenes. Some of the synthesized benzo[c]thiophenes exhibited strong solid-state fluorescence.
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书目信息
出版者
Oxford University Press
其它主题
Alkynes; Organic chemistry; Thiophenes
语言
英语
类型
Journal Article; Text
2024-02-28
MODS