Complementary Regioselectivity in Rh(III)-Catalyzed Insertions of Potassium Vinyltrifluoroborate via C–H Activation: Preparation and Use of 4-Trifluoroboratotetrahydroisoquinolones
2013
Presset, Marc | Oehlrich, Daniel | Rombouts, Frederik | Molander, Gary A.
Potassium vinyltrifluoroborate was found to be an efficient partner with benzamide derivatives for Rh(III)-catalyzed annulations. 4-Trifluoroboratotetrahydroisoquinolones were generated under mild conditions, affording a regioisomerically complementary substitution pattern to other alkenes in related reactions. These new boron-containing building blocks were derivatized by N-arylations, retaining the boron substituent for further elaboration.
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书目信息
出版者
American Chemical Society
其它主题
Carbon-hydrogen bond activation; Alkenes; Regioselectivity
语言
英语
许可
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类型
Journal Article; Text
2024-02-28
MODS