Organocatalytic enantioselective desymmetrization of cyclic enones via phosphine promoted [3+2] annulations
2010
Pinto, Nathalie | Retailleau, Pascal | Voituriez, Arnaud | Marinetti, Angela
Phosphine catalyzed enantioselective [3+2] cyclizations on 4-substituted 2,6-diarylidenecyclohexanones and 2,4-diarylidene-bicyclo[3.1.0]hexan-3-ones take place with high diastereo- and enantioselectivity levels. The process affords spirocyclic compounds with excellent stereochemical control of up to five stereogenic centres.
显示更多 [+] 显示较少 [-]AGROVOC关键词
书目信息
出版者
The Royal Society of Chemistry
其它主题
Enantioselectivity; Stereochemistry; Chemical communication
语言
英语
类型
Journal Article; Text
2024-02-28
MODS