High pressure assist-alkali pretreatment of cotton stalk and physiochemical characterization of biomass
2013
Du, Shuang-kui | Zhu, Xinna | Wang, Hua | Zhou, Dayun | Yang, Weihua | Xu, Hongxia
Ground cotton stalks were pretreated with sodium hydroxide (NaOH) at concentrations of 1–4% (w/v), pressures of 30–130kPa, durations of 15–75min, and liquid/solid ratios of 10:1–30:1. Modeling of the high pressure assist-alkali pretreatment (HPAP) of cotton stalk was attempted. The levels of NaOH concentration, pressure, and duration were optimized using a Box–Behnken design to enhance the cellulose content of treated solid residue. The optimum pretreatment conditions were as follows: liquid/solid ratio, 20:1; pressure, 130kPa; NaOH concentration, 3.0%; duration, 40min. During the conditions, cellulose content of pretreated cotton stalk residue was 64.07%. The maximum cellulose conversion of 45.82% and reducing sugar yield of 0.293g/g upon hydrolysis were obtained. Significant differences were observed in biomass composition and physiochemical characteristics between native and alkali-treated biomass. High NaOH concentration and pressure were conducive to lignin dissolution and resulted in increased cellulose content and conversion.
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