Effect of molding conditions and moisture content on the mechanical properties of compression molded glassy, wheat gluten bioplastics
2013
Jansens, Koen J.A. | Vo Hong, Nhan | Telen, Lien | Brijs, Kristof | Lagrain, Bert | Van Vuure, Aart Willem | Van Acker, Karel | Verpoest, Ignaas | Van Puyvelde, Peter | Goderis, Bart | Smet, Mario | Delcour, Jan A.
In absence or at low concentrations of plasticizer, high-temperature compression molded wheat gluten powder upon cooling vitrifies into a rigid material. Molding temperature (130–170°C range), molding time (5–25min range) and gluten powder moisture content (5.6–9.1% range) affect the mechanical properties of compression molded pieces. In this work, the relationship between the molding-induced gluten protein cross-linking and resulting mechanical properties was investigated as a function of the mentioned molding parameters. The flexural modulus was neither affected by any of the processing parameters nor by the resulting altered protein characteristics. In contrast, the strength and failure strain of samples prepared from gluten with the same moisture content increased with increasing degree of protein cross-linking and were maximal when compression molding for 5min at 170°C. Higher gluten powder moisture contents increased the cross-linking degree for molding at 130 and 150°C. The protein network degraded and the related mechanical properties worsened with longer molding times at 170°C. The extent of degradation increased when gluten powders with higher moisture content were molded.
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