Influence of titanium dioxide nanoparticles on the transport and deposition of microplastics in quartz sand
2019
Cai, Li | He, Lei | Peng, Shengnan | Li, Meng | Tong, Meiping
The influence of titanium dioxide nanoparticles (nTiO₂) on the transport and deposition of polystyrene microplastics (MPs) in saturated quartz sand was investigated in NaCl solutions with ionic strengths from 0.1 to 10 mM at two pH conditions (pH 5 and 7). Three different-sized polystyrene (PS) MPs (diameter of 0.2, 1, and 2 μm) were concerned in present study. We found that for all three different-sized MPs in NaCl solutions (0.1, 1 and 10 mM) at both pH 5 and 7, lower breakthrough curves and higher retained profiles of MPs with nTiO₂ copresent in suspensions relative to those without nTiO₂ were obtained, demonstrating that the copresence of nTiO₂ in MPs suspensions decreased MPs transport and increased their deposition in quartz sand under all examined conditions. The mechanisms contributing to the increased MPs deposition with nTiO₂ in suspensions at two pH conditions were different. The formation of MPs-nTiO₂ heteroaggregates and additional deposition sites provided by previously deposited nTiO₂ were found to drive to the increased MPs deposition with nTiO₂ in suspensions at pH 5, while the formation of MPs-nTiO₂ aggregates, additional deposition sites and increased surface roughness induced by the pre-deposited nTiO₂ on quartz sand surfaces were responsible for the enhanced MPs deposition at pH 7. The results give insights to predict the fate and transport of different-sized MPs in porous media in the copresence of engineered nanoparticles.
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