Optimization of Cu(II) Extraction from Aqueous Solutions by Soybean-Oil-Based Organic Solvent Using Response Surface Methodology

Chang, Siu Hua; Teng, Tjoon Tow; Ismail, Norli

Optimization of Cu(II) Extraction from Aqueous Solutions by Soybean-Oil-Based Organic Solvent Using Response Surface Methodology

2011

Chang, Siu Hua | Teng, Tjoon Tow | Ismail, Norli

This study aimed to optimize two process variables, namely extractant concentration, i.e., di-2-ethylhexylphosphoric acid concentration ([D2EHPA]) and equilibrium pH (pHeq), in Cu(II) extraction from aqueous solutions with a soybean-oil-based organic solvent using response surface methodology by maximizing the percentage extraction (%E). A central composite design was applied, and a regression model for %E was developed. Adequacy of the model was examined, and it was found to be statistically significant. The optimum conditions were determined as follows: [D2EHPA] of 84.71Â mM and pHeq of 4.46, which resulted in 99.78% of %E. The experimental value of %E (98.17%) obtained is found to agree satisfactorily with that (99.78%) predicted from the model.

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