Isolation and reactivity of a gold(i) hydroxytrifluoroborate complex stabilized by anion-π⁺ interactions
2021
Zhou, Jiliang | Litle, Elishua D. | Gabbaï, François P.
A 9,9-dimethylxanthene-based ligand substituted at the 4- and 5-positions by a phosphine and a xanthylium unit, respectively, has been prepared and converted into an AuCl complex, the structure of which reveals an intramolecular Au–Cl⋯π⁺ interaction. This new ligand platform was also found to support the formation of an unprecedented hydroxytrifluoroborate derivative featuring a “hard/soft” mismatched Au–μ(OH)–BF₃ motif. Despite its surprising stability, this gold hydroxytrifluoroborate complex is a remarkably potent carbophilic catalyst which readily activates alkynes, without activator.
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