Hexabromocyclododecane diastereoisomers in surface sediments from river drainage basins of Shanghai, China: occurrence, distribution, and mass inventory
2015
Tang, Liang | Shao, Hai-Yang | Zhu, Jian-Yao | Xu, Gang | Han, Tao | Peng, Bing-Quan | Wu, Ming-Hong
Concentrations of hexabromocyclododecanes (HBCDs) were determined in surface sediments of Shanghai, China. The concentrations of total HBCD diastereoisomers (ΣHBCD) ranged from 0.01 to 13.70 ng g⁻¹ dry weight (dw) with a mean value of 3.41 ng g⁻¹ dw, which was up to several orders of magnitude lower than those reported for sediments from European countries. The ΣHBCD concentrations in sediments from chemical/textile industrial or densely populated areas were generally higher than those from rural or less chemical/textile industrialized areas in Shanghai. A high proportion of α-HBCD was observed in sediment samples and was significantly higher than that of commercial HBCD products. This might be due to thermal isomerization from γ-HBCD to α-HBCD and slower degradation rate of α-HBCD compared to γ-HBCD in anaerobic conditions. The mass inventory of ΣHBCD in surface sediments of Shanghai was estimated at 164.4 kg, representing a significant source of HBCDs to the Shanghai environment. This indicates that further study on potential transfer of HBCDs from sediments to aquatic organisms and ecological risk assessments is required.
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