UV-Mediated Decomposition of Diazomalonates in Benzene: Unexpected Access to Functionalized Bicyclo[3.2.0]heptane Skeleton
2017
Chiang, Yi-Jung | Zhu, Jia-Liang
Upon irradiation with 300-nm UV light, the photolysis of diazomalonates in benzene unexpectedly affords 2,6-dicarboxylate bicyclo[3.2.0]hepta-2,6-dienes in low yields. These products are proven to be derived from cyclohepta-1,3,5-triene intermediates presumably via a tandem 1,5-carboxylate migration/[2 + 2] cycloaddition sequence.
显示更多 [+] 显示较少 [-]AGROVOC关键词
书目信息
Tetrahedron letters
ISSN
0040-4039
出版者
Elsevier Ltd
其它主题
Uv-mediated decomposition; Cycloheptatriene; Diazomalonates; Bicyclo[3.2.0]heptanes; Heptane
语言
英语
注释
Pre-press version
类型
Text; Journal Article
2024-02-28
MODS
