Transition metal-promoted biomimetic steps in total syntheses
2014
Li, Xu-Wen | Nay, Bastien
Covering: 1960 to present This review summarizes the state-of-the-art on the use of transition metals in synthetic steps inspired by biosynthesis. After an introduction showing the importance of metals in life processes, with special emphasis on biosynthetic processes, their place in biomimetic synthesis will be described. Topics include oxidative cyclizations for polyether synthesis, electrophilic and radical cyclizations of polyprenoids, the role of palladium in electrocyclizations, oxidative biaryl couplings and other rearrangement steps.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Lewis acids
语言
英语
类型
Journal Article; Text
2024-02-28
MODS