Facile synthesis of CoOOH@MXene to activate peroxymonosulfate for efficient degradation of sulfamethoxazole: performance and mechanism investigation
2022
Xia, Xinjing | Deng, Lin | Yang, Lingfang | Shi, Zhou
Using MXene as substrate, CoOOH@MXene with different mass content of CoOOH were prepared and used to active peroxymonosulfate (PMS) for the sulfamethoxazole (SMX) degradation. The sample characterizations demonstrated the successful preparation of CoOOH@MXene. CoOOH@MXene possessed much higher BET surface area (183.82 m²/g) than CoOOH (85.36 m²/g) and MXene (6.89 m²/g) due to the good dispersibility of CoOOH particles on MXene. Due to its large surface area, 1.3CoOOH@MXene displayed the best catalytic performance for the degradation of SMX. With 0.2 g/L of 1.3CoOOH@MXene and 0.5 mM of PMS, 20 μM of SMX was completely eliminated in 10 min. The degradation followed pseudo-first-order kinetic model well, with rate constants of 0.33 min⁻¹ for 1.3CoOOH@MXene and 0.054 min⁻¹ for CoOOH. Influencing factors of initial pH, catalyst dosage, PMS concentration, SMX concentration, and co-existing anions on SMX degradation were assessed systematically. Recycling tests verified the excellent reusability and stability of the catalyst. Quenching experiments and electron paramagnetic resonance analysis substantiated that ¹O₂ played a leading role. Moreover, the intermediates were identified, and degradation pathways and activation mechanism of CoOOH@MXene for PMS were proposed. This work may highlight the application of MXene with transition metals in PMS activation.
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