Preparation and application of porous nitrogen-doped graphene obtained by co-pyrolysis of lignosulfonate and graphene oxide
2015
Zhao, Hai-Bo | Wang, Wen-Dong | Lü, Qiu-Feng | Tan, Susie L. | Lin, Qilang | Yang, Haijun
Nitrogen-doped graphene with in-plane porous structure was fabricated by simple co-pyrolysis of lignosulfonate and graphene oxide in the presence of urea. Lignosulfonate first performs as a dispersant adsorbed on the surface of graphene oxide to prevent the aggregation of graphene oxide sheets for preparing homogeneous nitrogen-containing precursor, and then acts as a porogen to render graphene sheets with nanopores in the pyrolysis process of the nitrogen-containing precursor. Urea was used as a nitrogen source to incorporate nitrogen atoms into graphene basal plane. The special nanoporous structure combined with nitrogen content of 7.41at.% endows the nitrogen-doped graphene electrode material with super capacitance up to 170Fg−1, high rate performance, and excellent cycling stability.
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