Regioselective ortho-nitration of N-phenyl carboxamides and primary anilines using bismuth nitrate/acetic anhydride
2013
Lu, Yang | Li, Yaming | Zhang, Rong | Jin, Kun | Duan, Chunying
An efficient and one-pot synthetic method for the regioselective ortho-nitration of the N-phenyl carboxamides and primary anilines has been developed by using bismuth nitrate and acetic anhydride as the nitrating reagents. Reaction proceeds at room temperature and results in corresponding ortho-nitrated products in moderate to excellent yields. This method provides an operationally simple, regioselective, and efficient access to synthesize o-nitro anilines under the mild conditions.
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书目信息
出版者
Elsevier Ltd
其它主题
Bismuth nitrate; Dzanihzndhmhjc-uhfffaoysa-n; Ortho-nitration; Synthetic methods; Regioselectivity; Aromatic amines
语言
英语
类型
Journal Article; Text
2024-02-28
MODS