Supramolecular organogelators based on Janus type AT nucleosides
2013
He, Shiliang | Zhao, Hang | Guo, Xiurong | Xin, Guang | Huang, Baozhan | Ma, Limei | Zhou, Xinglong | Zhang, Rui | Du, Dan | Wu, Xiaohua | Xing, Zhihua | Huang, Wen | Chen, Qianming | He, Yang
J-AT nucleoside-based organogelators 1a and 1b were designed and synthesized. They were endowed with unparalleled superiority to natural nucleobase analogues 2–6 to gelate aromatic solvents due to their excellent self-assembly properties. The J-AT nucleoside-based organogelators showed a specific self-complementary base pair recognition characteristic. The gel stabilities of 1a and 1b were drastically influenced by adenine analogue 2, hardly affected by thymine analogue 3, uracil analogue 4, cytosine analogue 5, and mildly interrupted by guanine analogue 6.
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