Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts

Cheng, Qing-Qing; Zhu, Shou-Fei; Zhang, Yong-Zhen; Xie, Xiu-Lan; Zhou, Qi-Lin

Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts

2013

Cheng, Qing-Qing | Zhu, Shou-Fei | Zhang, Yong-Zhen | Xie, Xiu-Lan | Zhou, Qi-Lin

A copper-catalyzed B–H bond insertion reaction with amine– and phosphine–borane adducts was realized with high yield and enantioselectivity under mild reaction conditions. The B–H bond insertion reaction provides a new C–B bond-forming methodology and an efficient approach to chiral organoboron compounds.

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