Effective removal of non-steroidal anti-inflammatory drug from wastewater by adsorption process using acid-treated Fagopyrum esculentum husk
2022
Franco, Dison S. P. | Georgin, Jordana | Netto, Matias Schadeck | Foletto, Edson L. | Allasia, Daniel | Oliveira, Marcos L. S. | Pinto, Diana | Dotto, Guilherme L.
In this work, buckwheat husks (Fagopyrum esculentum) were modified by acid treatment and posteriorly employed to remove the ketoprofen in batch adsorption. The characterization results indicated that a more irregular surface with new empty spaces was generated after acid treatment. The adsorptive process was favored at acidic pH = 3. The dosage of 0.85 g L⁻¹ was fixed for the kinetic and isothermal tests, obtaining good removal and capacity indications. The kinetic studies were better represented by pseudo-second-order, obtaining an experimental capacity of 74.3 mg g⁻¹ for 200 mg L⁻¹ of ketoprofen. An increase in temperature negatively affected the adsorption isotherm curves, resulting in a maximum capacity of 194.1 mg g⁻¹. Thermodynamic results confirmed the exothermic nature of the process with physical forces acting. The adsorbent presented high efficiency in treating a synthetic effluent containing different drugs and salts, 71.2%. Therefore, adsorbent development from buckwheat husks treated with a strong acid is an excellent alternative, given the good removal results and the low cost for its preparation.
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