Thiol precursors in Vitis mould‐tolerant hybrid varieties

BACKGROUND: Over recent years, a new wave of disease‐tolerant to mildew varieties has flooded the viticulture sector, for reasons of human safety and economic expediency. These hybrid grape cultivars are selected mainly on the basis of their intrinsic capability to counter the attack of the main fungal diseases that affect grape production, such as downy mildew and powdery mildew. However, their organoleptic and oenological characteristics have not yet been studied in depth for purposes of both juice and wine production, due to the high number of newly proposed germplasms and the lack of information about their adaptability to different environments. This work examines the thiol aroma precursors concentration in 64 red and white disease‐tolerant hybrid varieties in the vine germplasm collections of Consiglio per la ricerca in agricoltura e l'analisi dell'economia agraria–Viticulture and Enology Research Center and Fondazione Edmund Mach, both from the north‐east of Italy. RESULTS: All cultivars showed the presence of 3‐mercaptohexan‐1‐ol (3MH) precursors, ranging from 4.4 to 1141 μg kg⁻¹ for 3‐S‐glutathionyl hexan‐1‐ol (GSH‐3MH), and from 0.3 to 136 μg kg⁻¹ for 3‐S‐cysteinyl 3‐hexan‐1‐ol. The concentration of GSH‐3MH exceeded 600 μg kg⁻¹ in eight varieties, with values comparable to those of the richest Vitis vinifera reported so far. On average, red grapes showed higher concentrations of 3MH precursors than white ones did. Only two hybrids had 4‐mercapto‐4‐methylpentan‐2‐one (4MMP) precursors over the limit of quantification, albeit with a much higher concentration than those normally reported in Sauvignon Blanc. CONCLUSION: This is the first detailed survey of 3MH and 4MMP precursors carried out taking into account a considerable number of hybrid grape varieties. The results show that some of these varieties could be interesting for the production of tropical juices or tropical‐aromatic wines and soft drinks, through the enzymatic liberation of thiol aromas, as well as for the production of aromatizing tannins to be used in the food industry. © 2020 Society of Chemical Industry