Sulfoxide and Sulfone Synthesis via Electrochemical Oxidation of Sulfides
2021
Park, Jin-Kyu | Lee, Sunwoo
The oxidation of diaryl sulfides and aryl alkyl sulfides to the corresponding sulfoxides and sulfones under electrochemical conditions is reported. Sulfoxides are selectively obtained in good yield under a constant current of 5 mA for 10 h in DMF, while sulfones are formed as the major product under a constant current of 10 or 20 mA for 10 h in MeOH. The oxygen of both the sulfoxide and sulfone function is derived from water.
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书目信息
出版者
American Chemical Society
其它主题
Organic chemistry; Sulfoxides
语言
英语
类型
Journal Article; Text
2024-02-28
MODS