Potassium hexacyanoferrate(ii)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides
2004
Schareina, Thomas | Zapf, Alexander | Beller, Matthias
A new advantageous cyanating agent, potassium hexacyanoferrate(ii), is described for the palladium-catalyzed cyanation of aryl halides. All cyanide ions on the iron(ii) center can be transferred to the aryl halide using palladium(ii) acetate and dppf as the catalyst. Under optimized reaction conditions good yields of benzonitriles and unprecedented catalyst productivities are observed.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Ferrocyanides
语言
英语
类型
Journal Article; Text
2024-02-28
MODS