Direct enantiomeric discrimination through antisymmetric hyperfine coupling
2021
Garbacz, Piotr | Vaara, Juha
Chiral open-shell molecules possessing permanent electric dipole moments have an EPR signal at the difference frequency of the electron and nuclear resonances, allowing direct enantiomeric discrimination by signal phase. The effect depends on the vector antisymmetry of the hyperfine coupling. Quantum chemistry suggests chiral bisfluorene methyl radical derivatives as promising for experiments.
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书目信息
Chemical communications
卷
57
期
67
页码
8264
- 8267
ISSN
1364-548X
出版者
The Royal Society of Chemistry
其它主题
Electrons; Couplings; Chemical communication
语言
英语
类型
Journal Article; Text
2024-02-28
MODS