Chemo- and Regioselective Distal Heteroaryl ipso-Migration: A General Protocol for Heteroarylation of Unactivated Alkenes
2017
Wu, Zhen | Wang, Dongping | Liu, Yuan | Huan, Leitao | Zhu, Chen
Herein we report a novel, general protocol for distal heteroaryl ipso-migration and its application to the elusive heteroarylation of unactivated alkenes. A set of nitrogen-containing heteroaryl groups showcase the migratory aptitude. This reaction provides a variety of fluoroalkyl functionalized heteroarenes under mild reaction conditions. This is the first report of a difunctionalization of unactivated alkenes with distal heteroaryl migration.
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书目信息
Journal of the American Chemical Society
卷
139
期
4
页码
1388
- 1391
ISSN
1520-5126
出版者
American Chemical Society
其它主题
Alkenes
语言
英语
类型
Journal Article; Text
2024-02-28
MODS