Poly(polyoxometalate)s assembled by {Ni₆PW₉} units: from ring-shaped Ni₂₄-tetramers to rod-shaped Ni₄₀-octamers

Huang, Ling; Zhang, Jie; Cheng, Lin; Yang, Guo-Yu

Poly(polyoxometalate)s assembled by {Ni₆PW₉} units: from ring-shaped Ni₂₄-tetramers to rod-shaped Ni₄₀-octamers

2012

Huang, Ling | Zhang, Jie | Cheng, Lin | Yang, Guo-Yu

Both structure-directing effect and synergistic-directing effect of PW₉O₃₄ fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni₂₄-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni₄₀-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

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