Terminal alkyne insertion into a thiolate-bridged dirhodium hydride complex derived from heterolytic cleavage of H₂
2018
Zhao, Xiangyu | Yang, Dawei | Zhang, Yahui | Wang, Baomin | Qu, Jingping
Thiolate-bridged dirhodium and diiridium complexes can facilely realize heterolytic cleavage of H₂ across the metal–sulfur bond to generate the corresponding hydride bridged complexes. Furthermore, terminal alkynes can insert the Rh–H–Rh fragment to afford σ:π alkenyl bridged complexes and then convert to the corresponding alkenes in the presence of a reductant and an acid.
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书目信息
Chemical communications
卷
54
期
79
页码
11112
- 11115
ISSN
1364-548X
出版者
The Royal Society of Chemistry
其它主题
Alkenes; Hydrides; Heterolytic cleavage; Alkynes; Reducing agents
语言
英语
类型
Journal Article; Text
2024-02-28
MODS