Formation of naphthalene hydrates in the enzymatic conversion of 1,2-dihydronaphthalene by two fungal peroxygenases and subsequent naphthalene formation
2014
Kluge, Martin | Ullrich, René | Scheibner, Katrin | Hofrichter, M. (Martin)
The formation of naphthalene hydrates (i.e. 1- and 2-hydroxy-1,2-dihydronaphthalene) displays a new activity (besides epoxidation) in the enzymatic transformation of 1,2-dihydronaphthalene by two fungal unspecific peroxygenases (UPOs) accounting for 16–19% of the overall turnover. These arene hydrates decayed into naphthalene that in turn was converted by UPOs into naphthols. The oxygen transferred during hydroxylation was shown to derive from hydrogen peroxide proving a true peroxygenation reaction.
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书目信息
Journal of Molecular Catalysis. B, Enzymatic
卷
103
页码
56
- 60
ISSN
1381-1177
出版者
Elsevier B.V.
其它主题
Unspecific peroxygenase; Aromatization; Naphthalene; Oxygenation; Naphthalene hydrates
语言
英语
类型
Journal Article; Text
2024-02-28
MODS