ZnCl2 catalyzed efficient synthesis of 1,3,4-oxadiazole and 1,3,4-thiadiazole
2014
Rahman, Md.A. | Karim, Mohammad R. | Arifuzzaman, Md | Siddiquee, Tasneem A. | Mirza, Aminul H.
New methods for the synthesis of 1,3,4-oxadiazole and 1,3,4-thiadiazole have been described. No cyclizations took place in the absence of ZnCl2. 1,3,4-Thiadiazoles are formed in the presence of ZnCl2 alone, whereas oxadiazoles are produced when a base such as Et3N or KOH was used along with ZnCl2. % Yields are optimized.
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书目信息
出版者
Elsevier Ltd
其它主题
Potassium hydroxide; Trimethylamine; 4-thiadiazole; Oxadiazoles; Phenanthroline; 4-oxadiazole
语言
英语
类型
Journal Article; Text
2024-02-28
MODS