One pot conversion of carbohydrates alcohol into chloride via benzotriazole sulfonate
2013
Azad, Chandra S. | Saxena, Anil K.
A one pot method for chloro-dehydroxylation of carbohydrates alcohol including sterically and electrically hindered ones in excellent yield was developed. The benzotriazole-1-sulfonate proposed to play a crucial role in the reaction medium, which undergoes substitution by chloride ion in the reaction medium to give only desired chloride derivative without the formation of side product. The optimized methodology can be used in the synthesis of number of biologically active compounds or chiral synthones.
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书目信息
出版者
Elsevier Ltd
其它主题
Deoxyhalogeno-carbohydrate; Appel reaction; Alcohols to chloride; Bezotriazole-1-sulfonate
语言
英语
类型
Journal Article; Text
2024-02-28
MODS