Palladium-catalyzed oxidative tandem reaction of allylamines with aryl halides leading to α,β-unsaturated aldehydes
2009
Jiang, Tao-Shan | Li, Jin-Heng
A novel tandem protocol involving a Heck reaction process for the synthesis of α,β-unsaturated aldehydes has been developed. In the presence of Pd(OAc), PPh₃, NaOAc, TBAB and air, N-allylbenzenamines underwent the reaction with various aryl halides to afford the corresponding α,β-unsaturated aldehydes selectively in moderate to good yields. The protocol can also be used as a valuable route for the deallylation of arylamines.
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书目信息
Chemical communications
期
46
页码
7236
- 7238
ISSN
1364-548X
出版者
The Royal Society of Chemistry
其它主题
Chemical communication; Aromatic amines
语言
英语
类型
Journal Article; Text
2024-02-28
MODS