Simultaneous removal of organic and inorganic pollutants from water by Ni/NiO/SnO2 nanoparticles
2022
Shivangi, | Bhardwaj, Siddhant | Sarkar, Tapan
Herein, we report a facile synthesis of Ni/NiO/SnO₂ hybrids where the core–shell-type Ni/NiO nanoparticle is decorated with the SnO₂ nanoparticle to make a heterojunction and their potential evaluation for simultaneous removal of organic and inorganic pollutants. The metallic nickel core of the nanoparticle helps to separate easily from water magnetically and restricts the possible secondary contamination. The formation of semiconductor–semiconductor heterojunction enhances the photocatalytic activity to degrade the organic pollutants. The nanomaterial was characterized using microscopic, spectroscopic, and BET analyses. Results indicated an efficient degradation of ~ 94% of crystal violet in 40 min. An adsorption capacity of ~ 530 mg g⁻¹ and ~ 650 mg g⁻¹ of cadmium and lead ions, respectively, was found for single-component adsorption experiments, and ~ 520 mg g⁻¹ and ~ 720 mg g⁻¹ of cadmium and lead ions, respectively, were found for multi-component experiments. This observation suggested that the lead and cadmium ion adsorption process is affected by the synergistic and antagonistic effects, respectively. However, no significant change in the photocatalytic activity was observed for multi-component experiments. Results indicated that the process followed the Langmuir isotherm and pseudo-second-order kinetics irrespective of the number of pollutants present. An excellent adsorption capacity of metal ions and photodegradation capability of organic dye in multi-component solution, and possible reusability of the nanoparticle, make the Ni/NiO/SnO₂ a potential material for simultaneous removal of organic and inorganic pollutants.
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