Transformation of N,N-diisopropylarylmethylamines into N-isopropylarylmethylamines with molecular iodine

Ezawa, Masatoshi; Moriyama, Katsuhiko; Togo, Hideo

Transformation of N,N-diisopropylarylmethylamines into N-isopropylarylmethylamines with molecular iodine

2015

Ezawa, Masatoshi | Moriyama, Katsuhiko | Togo, Hideo

N,N-Diisopropylarylmethylamines were smoothly converted into the corresponding N-isopropylarylmethylamines by the reaction with molecular iodine in the presence of Na2CO3 in chloroform at 60°C. Other related tertiary amines were also transformed into the corresponding secondary amines by the reaction with molecular iodine under the same reaction conditions.

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