Total Synthesis of (−)-Ambiguine P
2019
Xu, Jiasu | Rawal, Viresh H.
Described is a concise total synthesis of (−)-ambiguine P, a cycloheptane-containing member of the hapalindole alkaloids. The challenging pentacyclic framework of the natural product was assembled rapidly via a [4 + 3] cycloaddition reaction-inspired strategy, and the tertiary hydroxy group was introduced by an NBS-mediated bromination–nucleophilic substitution sequence.
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书目信息
出版者
American Chemical Society
其它主题
Cycloaddition reactions
语言
英语
类型
Journal Article; Text
2024-02-28
MODS