Induced crystallization of cellulose in never-dried cotton fibers
1991
Bhama Iyer, P. | Sreenivasan, S. | Chidambareswaran, P.K. | Patil, N.B. | Cuntaram, Vi
In the present investigation, we have made a systematic study of the induced crystallization in never-dried cotton fiber, by allowing it to desiccate under different conditions of humidity and temperature. The resulting structural changes have been followed using x-ray diffraction and infrared absorption techniques. A slow rate of drying coupled with a high temperature was more conducive for maximum crystallization. Analysis of the effect of temperature on the induced crystallization showed possible existence of a thermal transition in cellulose around 30 degrees C. The induced crystallization brought about by slow drying as well as those produced using intercrystalline swelling agents, have been shown to be resulting from a proper channelization of the interfibrillar mobility existing in the never-dried fibers.
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