Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

Jana, Atanu; Ishida, Masatoshi; Cho, Kevin; Ghosh, Sudip Kumar; Kwak, Kyuju; Ohkubo, Kei; Sung, Young Mo; Davis, Christina M.; Lynch, Vincent M.; Lee, Dongil; Fukuzumi, Shunichi; Kim, Dongho; Sessler, Jonathan L.

Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

2013

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.

显示更多 [+]