240Pu/239Pu atom ratios in water columns from the North Pacific Ocean and Bering Sea: Transport of Pacific Proving Grounds-derived Pu by ocean currents

The ²⁴⁰Pu/²³⁹Pu atom ratios in seawater from the northern North Pacific Ocean and Bering Sea were determined to elucidate the temporal variability in ²³⁹⁺²⁴⁰Pu inventory, to identify their Pu sources and to propose the transport pathway of Pacific Proving Grounds (PPG)-derived Pu into the studied area. Water column ²³⁹⁺²⁴⁰Pu inventory in the Bering Sea was lower than that reported for a comparable station in the Geochemical Ocean Sections Study, indicating that the Bering Sea inventory has been decreasing at the average rate of 2.6 Bq m⁻² yr⁻¹. The ²⁴⁰Pu/²³⁹Pu atom ratios ranged from 0.222 to 0.255 with a mean value of 0.235 in the northern North Pacific Ocean and from 0.215 to 0.237 with a mean value of 0.224 in the Bering Sea. The obtained ²⁴⁰Pu/²³⁹Pu ratios were clearly higher than the mean global fallout ratio of 0.18. These high atom ratios proved the presence of close-in fallout Pu from nuclear weapons testing at the PPG. The relative contribution of the global fallout and the PPG fallout were evaluated by using the two-end-member mixing model. The ²³⁹⁺²⁴⁰Pu inventories originating from the PPG fallout were calculated as 17.9–25.4 Bq m⁻² in the northern North Pacific Ocean and 11.6–16.6 Bq m⁻² in the Bering Sea, which corresponded to 38–54% and 31–45% of the total ²³⁹⁺²⁴⁰Pu inventory in the water column in the northern North Pacific Ocean and Bering Sea, respectively. A significant amount of the PPG-derived Pu has been transported to the northern North Pacific Ocean and Bering Sea. The proposed transport pathway accounting for the high ²⁴⁰Pu/²³⁹Pu ratio in the Bering Sea water column is the transportation of PPG-derived Pu by the North Equatorial Current followed by the Kuroshio Current, Kuroshio Extension, North Pacific Current and subsequently the Alaska Current, and then the Alaskan Stream.